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    Confinement of Perovskite-QDs within a Single MOF Crystal for Significantly Enhanced Multiphoton Excited Luminescence

    Editor:yingwen Date:2018-12-19 Hits:138

     

    Huajun He, Yuanjing Cui, Bin Li, Bo Wang, Chuanhong Jin, Jiancan Yu, Lijia Yao, Yu Yang, Banglin Chen,* and Guodong Qian*[Advanced Materials]

    The development of the photostable higher-order multiphoton-excited (MPE) upconversion single microcrystalline material is fundamentally and technologically important, but very challenging. Here, up to five-photon excited luminescence in a host¨Cguest metal¨Corganic framework (MOF) and perovskite quantum dot (QD) hybrid single crystal ZJU-28⊃MAPbBr3 is shown via an in situ growth approach. Such a MOF strategy not only results in a high QD loading concentration, but also significantly diminishes the aggregationcaused quenching (ACQ) effect, provides effective surface passivation, and greatly reduces the contact of the QDs with the external bad atmosphere due to the confinement effect and protection of the framework. These advantages make the resulting ZJU-28⊃MAPbBr3 single crystals possess high PLQY of ˇÖ51.1%, a high multiphoton action cross-sections that can rival the current highest record (measured in toluene solution), and excellent photostability. These findings liberate the excellent luminescence and nonlinear optical properties of perovskite QDs from the solution system to the solid singlecrystal system, which provide a new avenue for the exploitation of highperformance multiphoton excited hybrid single microcrystal for future optoelectronic and micro¨Cnano photonic integration applications.

    DOI: 10.1002/adma.201806897



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